Research Article

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2015, 8(11): 3472–3479

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https://doi.org/10.1007/s12274-015-0845-4

NiRh nanoparticles supported on nitrogen-doped porous carbon as highly efficient catalysts for dehydrogenation of hydrazine in alkaline solution

Bingquan Xia1, Kang Chen1, Wei Luo1,2 (*), and Gongzhen Cheng1

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1 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, China
2 Suzhou Institute of Wuhan University, Suzhou, Jiangsu 215123, China

Keywords: hydrogen storage,metal–organic frameworks,nitrogen-doped porouscarbon,hydrazine
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  • Abstract
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Well-dispersed bimetallic NiRh nanoparticles (NPs) with different compositions supported on nitrogen-doped porous carbon (NPC) derived from metal–organic frameworks (ZIF-8) were synthesized through a co-reduction method. The NPC-900 supported NiRh catalyst exhibits the highest catalytic activity and 100% hydrogen selectivity toward hydrogen generation from hydrazine. These properties might be attributed to the high surface area and high graphitization of the NPC. This strategy may open up a new avenue for designing high-performance catalysts by utilizing NPC as a support to anchor active metal NPs for additional applications.
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NiRh nanoparticles supported on nitrogen-doped porous carbon as highly efficient catalysts for dehydrogenation of hydrazine in alkaline solution. Nano Res. 2015, 8(11): 3472–3479 https://doi.org/10.1007/s12274-015-0845-4

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