Research Article

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2017, 10(11): 3638–3647

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https://doi.org/10.1007/s12274-017-1574-7

Confined reaction inside nanotubes: New approach to mesoporous g-C3N4 photocatalysts

Xueteng Liu, Fei Pang, Mingyuan He, and Jianping Ge (*)

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Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

Keywords: photocatalysis, g-C3N4, confined reaction, mesoporous
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ABSTRACT Mesoporous g-C3N4 nanorods (NRs) are synthesized through the nano-confined thermal condensation of cyanamide in silica nanotubes (NTs) with porous shells. The gas bubbles retained during condensation and the limited cyanamide precursor inside the silica NTs lead to the formation of mesoporous g-C3N4. This nano-confined reaction is an alternative method to the traditional templating process for the synthesis of mesoporous materials. The as-prepared mesoporous g-C3N4 NRs exhibit remarkably improved photocatalytic activity and high stability in water splitting and degradation of Rhodamine B compared with bulk g-C3N4.
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Confined reaction inside nanotubes: New approach to mesoporous g-C3N4 photocatalysts. Nano Res. 2017, 10(11): 3638–3647 https://doi.org/10.1007/s12274-017-1574-7

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