Research Article

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2018, 11(4): 2034–2045

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https://doi.org/10.1007/s12274-017-1820-z

Dual-mode emission of single-layered graphene quantum dots in confined nanospace: Anti-counterfeiting and sensor applications

Liqian Bai1, Ning Xue1, Yufei Zhao2, Xinrui Wang3, Chao Lu1, and Wenying Shi1 (*)

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1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, 15 Beisanhuan East Road, Beijing 100029, Beijing, China
2 Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, Beijing, China
3 Beijing Key Lab of Plant Resource Research and Development, Beijing Technology and Business University, Beijing 100048, Beijing, China

Keywords: graphene quantum dots, dual-mode emission, confinement, sensors, anti-counterfeiting
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  • Abstract
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ABSTRACT Engineering of the luminescent properties for graphene quantum dots (GQDs) presents two enormous challenges: 1) The bandgap of GQDs is mainly determined by structural defects (size, shape, and the fraction of sp2 and sp3 domains), which results in non-stoichiometric nature; 2) the preparation methods limit the achievement of an accurate chemical structure of GQDs, leading to many controversial explanations over the relationship between the structural defects and bandgaps. Here, single-layered GQDs with an exact structure are obtained by in-situ reaction of intercalated precursors in the confined nanospace of layered double hydroxides (LDHs). Subsequently, the structure-property relationship is uncovered, demonstrating the enhanced fluorescence and activated room temperature phosphorescence of the as-prepared GQDs-LDHs, which originate from synergistic effects: 1) strong confinement provided by the nanospace of LDHs; 2) rich O-containing functional groups on the surface of GQDs resulting from LDH catalysis. Moreover, the colorless nature and dual-emission characteristics of GQDs-LDHs satisfy the preconditions as anti-counterfeiting markers for protecting valuable documents (bank notes, commercial invoices, etc.). Particularly, owing to the low toxicity of GQDs and the edible property of LDHs, the GQDs-LDHs/gelatin capsules could be the new generation of potential green anti-counterfeiting material in the field of food and drugs.
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Dual-mode emission of single-layered graphene quantum dots in confined nanospace: Anti-counterfeiting and sensor applications. Nano Res. 2018, 11(4): 2034–2045 https://doi.org/10.1007/s12274-017-1820-z

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