Review Article

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2019, 12(9): 2067–2080

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https://doi.org/10.1007/s12274-019-2345-4

Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion

Tingting Sun1, Lianbin Xu2, Dingsheng Wang1 (*), and Yadong Li1

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1 Department of Chemistry, Tsinghua University, Beijing 100084, China
2 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Keywords: single atom catalysts, metal organic frameworks, electrocatalytic, energy conversion
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  • Abstract
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The development of efficient and cost-effective catalysts to catalyze a wide variety of electrochemical reactions is key to realize the large-scale application of renewable and clean energy technologies. Owing to the maximum atom-utilization efficiency and unique electronic and geometric structures, single atom catalysts (SACs) have exhibited superior performance in various catalytic systems. Recently, assembled from the functionalized organic linkers and metal nodes, metal-organic frameworks (MOFs) with ultrafine porosity have received tremendous attention as precursors or self-sacrificing templates for preparing porous SACs. Here, the recent advances toward the synthesis strategies for using MOF precursors/templates to construct SACs are systematically summarized with special emphasis on the types of central metal sites. The electrochemical applications of these recently emerged MOF-derived SACs for various energy-conversion processes, such as oxygen reduction/evolution reaction (ORR/OER), hydrogen evolution reaction (HER), and CO2 reduction reaction (CO2RR), are also discussed and reviewed. Finally, the current challenges and prospects regarding the development of MOF-derived SACs are proposed.
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Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion. Nano Res. 2019, 12(9): 2067–2080 https://doi.org/10.1007/s12274-019-2345-4

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